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酞菁氧钛的合成及晶型转化
An Improved Method for Oxotitanium Phthalocyanine Preparation
【摘要】 酞菁氧钛以联环己烷为溶剂,以邻苯二脂及四氯化钛直接反应生成。其优点是便于分离及纯化。同时对各晶型的获得及晶型间的相互转化进行了研究,并以X-射线粉末衍射及FT-IR进行了表征,并记录了不同晶型的酞菁氧钛在室温硫化硅橡胶中的吸收光谱。
【Abstract】 Oxotitanium phthalocyanine was synthesized from phthalonitrile and titanium te-trachloride in bicyclohexyl.It is much more convenient to separate and purify the productsby using bicyclohexyl as a solvent. Five polymorphs were obtained and characterized by X-ray powder diffractometry and FTIR spectroscopy. The absorption spectra of the poly-morphs in silicone rubbers were recorded.
【关键词】 酞菁氧钛;
合成;
晶型;
有机光导材料;
【Key words】 oxotitanium phthalocyanine; synthesis; crystal form; organic photoconductor;
【Key words】 oxotitanium phthalocyanine; synthesis; crystal form; organic photoconductor;
- 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,1994年01期
- 【分类号】O627.43
- 【被引频次】16
- 【下载频次】229