【摘要】 本文通过双（2-甲氧乙基环戊二烯基）稀土氯化物与环戊二烯基钠在室温下反应,经升华得新配合物,（CH₃OCH₂CH₂C₅H₄）₂Ln（C₅H₅）（Ln=La,Pr,Nd）,这些配合物都经红外、光电子能谱、质谱、核磁共振谱和元素分析鉴定;并且比较了具有不同配位环境的三茂稀土配合物-氢化钠体系还原1-己烯的活性。更多还原

【Abstract】 The complexes (CH3OCH2CH2C5H4)2Ln(C5H5)(Ln = La, Pr, Nd)were synthesized via the reaction of bis(2-methoxylethylcyclopentadienyl) chlorides of early lanthanide with sodium cyclopentadienyl in THF. The new complexes were identified by IR, 1H NMR, 13C NMR, MS, XPS and elemental analyses. Reduction of 1-hexene with different tricyclopentadienyl lanthanides/ NaH system was investigated. The reducing activity depends strongly upon the coordination sphere of the rare earth ion.更多还原