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中性磷萃淋树脂吸附铼的性能和机理研究ⅢCL-P_(350)-KReO_4-HNO_3体系

Study on the Property and Mechanism of Adsorption Rhenium by Using Neutral Phosphorous-Based Levextyel Resin Ⅲ

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【作者】 何焕杰王连英马雅雅王永红詹适新韩燕

【Author】 He Huanjie Wang Lianylng Ma Yaya Wang Yonghong Zhan Shixin Han Yan

【机构】 中原石油学校实验室

【摘要】 本文报道四甲基膦酸二甲庚酸萃淋树脂(CL-P_(350)从硝酸溶液中吸附鳞的性能和机理研究。实验结果表明,吸附平衡服从Langmuir经验等温式。测得吸附物分子中P(350)与Re(Ⅶ)的摩尔比为2:1。Re(Ⅶ)是以形式被树脂吸附,其吸附机理属于综合反应:并测定了吸附过程的热力学函数。

【Abstract】 The property and mechanism of adsorpting rhenium from aqeous nitric acid was reported by using methyl phosphorous acid dimethyl heptyl ester levextrel resin(CL-P350).Experimental results showed that the adsorption of the resin for Re(Ⅶ)can be de scribed by Langmuir’s equation of the equilibrium State. By means of Chemical analysis,the molar ratio of P350 to Re(Ⅶ)in the adsorption molecular determined was 2:1.IR analysis in-dicated that ReO was taren up by ionic association mechanism:and the therimodynamic functions in the adsorption process of ReO have been determined.

  • 【文献出处】 信阳师范学院学报(自然科学版) ,JOURNAL OF XINYANG TEACHERS COLLEGE(NATURAL SCIENCE EDITION) , 编辑部邮箱 ,1994年03期
  • 【分类号】O614.713
  • 【下载频次】59
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