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盐湖盐类水溶液298.15K时稀释热和表观摩尔焓的研究

Enthalpies of Dilution and Relative Apparent Molal Enthalpies of the Major Aqueous Salts of Salt Lakes at 298.15K

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【作者】 李积才翟宗玺曾忠民王鲁英

【Author】 Li Jicai; Zhai Zongxi; Zeng Zhongmin; Wang Luying(Qinghai Institute of Salt Lakes, Academia Sinica, Xining 810001)

【机构】 中国科学院青海盐湖研究所!西宁810008

【Abstract】 The heat of dilution of aqueous solution of the chloride(KCl, NaCl, MgCl2,CaCl2) and sulfate (Na2SO4, K2SO4, MgSO4) of Salt Lakes were measured over a concentration range of 0.05-2.1mol. kg-1 at 298.15K. The data were extrapolated to indrite dilution by use of the Debye-Hhckel lindtion law to obtain relative apparent molal enthalpies (Li). The enthalpies of dilution were calculated using the ion interaction model of Pitzer. The experimental enthalpies (△He) were compared with calculated values (△Hc)of dilution.

【基金】 国家自然科学基金
  • 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,1994年08期
  • 【分类号】O642
  • 【被引频次】9
  • 【下载频次】73
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