节点文献
两种新型植物激素燃烧热的测定及生成焓的计算
CALCULATION ON ENTHALPIES OF STANDARD FORMATION OF TWO NEW PLANT HORMONES
【摘要】 本文报道了用精密转动弹量热计测定两种新型植物激素2-[2-氯苯胺基)羰基]苯甲酸与Ni(Ⅱ)、Cu(Ⅱ)的配合物的燃烧热,换算得Ni(Ⅱ)、Cu(Ⅱ)配合物的分别为11881.1±6.9,13206.7±7.5KJ·mol-1,计算得它们的分别为2050.5±6.9.639.7±7.5kJ·mol-1.
【Abstract】 Using a precision rotating-bomb combustion calorimeter, the heats of combustion of twonew plant hormones, the complexes of 2-[(2-chlorophenyl)amino carbonyl] benzoic acid withNi(Ⅱ) and Cu(Ⅱ), were determined tO be-11881. 1±6.9 and -13224.1 ±7.5kJ. mol-1 respectively, the precision of the results being given in s. d. m.. The enthalpies of formation of thesecomplexes have been calculated to be-2094.7±6.9 and -964.6 ±7.5kJ. mol-1 respectively.
【关键词】 配合物;
燃烧热;
生成焓;
植物激素;
【Key words】 complex heat of combustion enthalpy of formation plant hormone;
【Key words】 complex heat of combustion enthalpy of formation plant hormone;
【基金】 国家自然科学基金
- 【文献出处】 无机化学学报 ,JOURNAL OF INORGANIC CHEMISTRY , 编辑部邮箱 ,1994年01期
- 【分类号】Q946.885
- 【被引频次】6
- 【下载频次】85