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合成气在K-Fe-MnO/Silicalite-2催化剂上转化为低碳烯烃的研究 I.K2O助剂的作用

Production of light alkenes from syngas over K-Fe-MnO/silicalite-2 catalyst I. Effect of K2O promoter

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【作者】 徐龙伢王清遐杨力赵修松徐奕德黄家生

【Author】 Xu Longya; Wang Qingxia;Yang Li; Zhao Xiusong(Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023)Xu Yide; Huang Jiasheng(State Key Laboratory of Catalysis, DalianInstitute of Chemical Physics, Chinese Academy of Sciences, Dal

【机构】 中国科学院大连化学物理研究所

【摘要】 K2O是催化剂Fe-MnO/Silicalite-2由合成气制低碳烯烃的有效助剂,K2O能明显提高催化剂活性及低碳烯烃选择性。K2O助剂将抑制部分铁的还原,但能增强催化剂对CO的吸附能力,从而能提高催化剂活性,抑制甲烷的生成,K2O助剂能抑制乙烯在催化剂表面的二次反应(尤其是乙烯的歧化反应),从而提高CO/H及反应制低碳烯烃的选择性。

【Abstract】 K2O is an available promoter for production of light alkenes from syngas over FeMnO/silicalite-2 catalyst, and it can obviouslyimprove both catalyst activity and selectivityto alkenes. K2O may prohibit reduction of Fepartially, but it can strengthen adsorption ofCO on the catalyst, which is favorable for en-hancing the activity of the catalyst and suppressing the formation of CH4. K2O can increase the selectivity of CO hydrogenation tolight alkenes by inhibiting the secondary reactions of C2H4 on the surface of the catalyst,especially the disproportionation of C2H4.

【基金】 国家“八·五”重点科技攻关课题
  • 【文献出处】 天然气化工 ,Natural Gas Chemical Industry , 编辑部邮箱 ,1994年06期
  • 【分类号】TQ426.94
  • 【被引频次】12
  • 【下载频次】259
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