【摘要】 作为表面化学四大方程之一的Thomson方程,近年来在某些推证上出现概念上错误,因而甚至企图否认该方程的正确性。为此,本文阐述了各种可行的推导方法,肯定优点,指出缺点;对某些不妥当的说法、不公正的批评提出商榷;力图澄清概念上的混乱,阐明该方程的正确性。著者并提出了一种应用蒸气压随外压的变化率关系式来推证Thomson方程的简明方法。更多还原

【Abstract】 As one of the four principal equations of surface chemistry, the Thomson equation has recently been deduced by somebody with crrior concepts, therefore the correctness of the equation is suspected. In order to clarify the conceptual confusion, various workable deduction methods have been reviewed, in which the advantgcs and defects arc discussed, and the incorrcctcd criticisms and formulations arc open to question. A concise deduction method has been suggested by the author.更多还原