【摘要】 用分光光度法研究了镧系离子Ｌｎ３＋（Ｎｄ３＋，Ｈｏ３＋，Ｅｒ３＋）与１－苯基－３－甲基－４－苯甲酸基吡唑酮－５（ＨＰＭＢＰ）和２，２＇－联吡啶（Ｄｉｐｙ）在乙醇－水溶液中配合物的组成和超灵敏跃迁．合成了镧、铈、镨、钕、钐、铕与ＨＰＭＢＰ和Ｄｉｙｙ的三元配合物；考察了配合物的红外光谱、热稳定性等．更多还原

【Abstract】 The composition and hypersensitive transition of ternary coordination compounds of lanthanides (Nd3+, Ho3+ and Er3+) with 1-pheny1-3-methy1-4-benzoy1-5-pyrazolone (HPMBP) and dipyridine (Dipy) in ethanolic-water solvent system have been studied by spectrophotometrv. The solid state ternary coordination compounds of lanthanide (La3+,Ce3+, Pr3+ .Nd3+, Sm3+ and Eu3+) with HPMBP and Dipy are prepared and analyzed by the elemental analysis. It is proved that the component ratio of Ln: HPMBP: Dipy in ternary coordination compound is 1: 3: 1. The infrared spectra thermostability and solubility of solid state compounds have been investigated.更多还原