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海泡石的酸改性和性能研究——Ⅲ.作为FCC催化剂组分催化作用的初步探讨

ACID MODIFICATION OF SEPIOLITE AND ITS PROPERTIES Ⅲ. MODIFIED SEPIOLITE AS A COMPONENT OF FCC CATALYST

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【作者】 蒋文斌刘德义屠式瑛

【Author】 Jiang Wenbin Liu Deyi Tu Shiying (Research Institute of Petroleum Processing)

【机构】 石油化工科学研究院石油化工科学研究院

【摘要】 研究了酸改性海泡石作为裂化催化剂组分对催化剂烃反应性能的影响以及其抗钒性能,并对海泡石中杂质的催化作用进行了初步的考察。结果表明.海泡石经酸改性后.基本能抑制REY分子筛骨架的破坏;酸改性海泡石水蒸气条件下适当降低了REY分子筛表面酸密度,从而对氢转移、生焦反应有所抑制。经酸改性海泡石的抗钒能力有所增强。海泡石中杂质铁导致了它的脱氢活性。

【Abstract】 Hydrocarbon reactions on modified sepiolite as FCC catalyst component and its antivanadium behavior have been studied. The results show that acid modification can alleviate the damage of REY structure under hydrothermal conditions and also decrease its acid density, thus hydrogen tranfer and coke formation are to some extent inhabited. Evidence of anti-vanadium ability of sepiolite is observed, and Fe existed as impurity in sepiolite causes dehydrogention of hydrocarbons.

  • 【文献出处】 石油学报(石油加工) ,Acta Petrolei Sinica(Petroleum Processing Section) , 编辑部邮箱 ,1994年03期
  • 【分类号】O643.36
  • 【被引频次】19
  • 【下载频次】148
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