【摘要】 研究了有机硫代磷酸酯的大孔阴离子交换柱色谱族组分分离、ＨＰＬＣ单体组分分析以及半制备ＨＰＩ工单体组分分离方法，同时给出了各种硫代磷酸酯的ＵＶ光谱、ＩＲ光谱、ＮＭＲ和ＦＤＭＳ特征。更多还原

【Abstract】 nalytical methods for organic thiophosphate additives including monothiophosphates, dithiophosphatesand complex thiophosphates in lubricants were studied. Thiophosphates were first isolated as a class by non-aqueous macroporous anion exchange column chromatography,then separated into individuals by semi-preparative reversed phase HPLC. Structural identifications of separated thiophosphate individuals were atlast accomplished by UV,FTIR,P￣(31)-NMR,H￣1-NMR,C￣(13)-NMR and FDMS etc.Analytical HPLC of thiophos-phates and their UV absorption,FTIR,NMR and FDMS characteristics are also discussed.更多还原