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稀土钇提高离子镀TiN膜层与基体结合力的研究
Research on Bond Strength between Ion Plated TiN Coating and Substrate Improved by Rare Earth Y
【摘要】 研究了稀土钇不同含量时对离子镀TiN膜层与基体结合力的影响.用扫描电镜,俄歇谱仪,X射线衍射等手段,对加入稀土钇的TiN膜层作了分析。结果表明,加适量稀土钇后,TiN膜层与基体的结合力大大提高。其微观机制是,加稀土钇后,膜层相组成发生变化,在膜-基之间形成一过渡层,塑性相(Ti相)增加,脆性相(Ti2N)减少,从而减小了膜-基界面间的应力。此外,结果还表明,稀土钇能明显提高镀膜过程中钛料蒸发率,使成膜速率增加,在相同镀膜时间内TiN膜层加厚。
【Abstract】 Deals with the effect of rare earth Y of different contents on the bond strength between the ion plated TiN coating and the substrate.Ti (Y)N coating is examined by means of SEM,Auger energy and X-ray microdiffraction.The results show that the bond strength between the TiN coating and the substrate increases greatly by adding moderate amount of rare earth Y. The micro--mechanism is that adding rare earth Y brings about change in the composition of the coating phase and a transition layer is formed between the coating--substrate,which increases the ductility phase(Ti phase)and decreases the fragility phase (Ti2N), thus decreasing the bond strength between the coating--substrate. In addition,the rare earth Y can obviously increases the evaporating rate of titanium during the process of ion plated coating and increases the rate of forming the coating. The ion plated coating remains the same.
【Key words】 rare earth elements; ion plating; bond stress; X-ray spectrum; evaporating rate;
- 【文献出处】 南京航空航天大学学报 ,TRANSACTIONS OF NANJING UNIVERSITY OF AERONAUTICS & ASTRONAUTICS , 编辑部邮箱 ,1994年05期
- 【分类号】TG115.31
- 【被引频次】5
- 【下载频次】115