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聚苯乙烯固载聚乙二醇在邻苯二甲酰亚胺的N-烃基化反应中的相转移催化作用
A Study on the Phase Transfer Catalytic Effects of Polystyrene Supported Polyethylene Glycols on the N-alkylation of Phthalimide
【摘要】 本文报道了聚苯乙烯固载聚乙二醇作为相转移催化剂催化合成N-烃基邻苯二甲酰亚胺。在无水碳酸钾、无水氟化钾、乙腈和聚苯乙烯固载聚乙二醇400或聚苯乙烯固载吡啶盐一聚乙二醇400等作用下,合成了三种N-烃基邻苯二甲酰亚胺。
【Abstract】 Abstract: This paper reports the synthesis of the N-alkyl derivatives of phthalimide using polystyrene supported polyethylene glycols (PS-PEG)as phase transfer catalysts. Three N-alkyl phthalimides were obtained by the phase transfer catalytic reaction of phthalimide with the appropriate alkyl handes in the presence of potassium carbonate,potassium fluoride,acetonitrile and the polystyrene supported polyethylene glycol-400 (PS-PEG-400)or the polystgrene supported pyridinium salt and PEG-400(PS-PY PEG-400),etc.
- 【文献出处】 离子交换与吸附 ,Ion Exchange and Adsorption , 编辑部邮箱 ,1994年02期
- 【分类号】O643.3
- 【被引频次】7
- 【下载频次】124