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α-水芹烯-马来酸酐加成物(PM)及N-烷基亚酰胺(PMR)的制备
PREPARATION OF ADDUCT OF α-PHELLANDRENE WITH MALEIC ANHYDRIDE(PM)AND N-2-ETHYLHEXYLIMIDE(PMR)
【摘要】 首次由α-蒎烯和马来酸酐的加成产物中分离出α-水芹烯-马来酸酐加成物(PM)。在常压下,PM和氢气反应,合成二甲酰亚胺(PMN)。然后,利用相转移催化技术,由PMN合成N-(2-乙基)己基亚酰胺(PMR),这一合成方法未见文献报道。通过IR、MS和 ̄1HNMR分析,证实了产物的结构。
【Abstract】 Adduct of α-phellandrene with maleic anhydride(PM)was first isolated from the product of α-pinene and maleic anhydridc. The synthesis of imide(PMN) was performed by reaction of PM and NH3undct atmospheric pressure. And then,N-2-ethylhexylimide(PMR) was synthesized in the presence of phasetransfer caralyst (PTC).The synthetic method of PMR with PTC has not been reported in the lieratures.The structures of products were identified by IR,MS and  ̄1H NMR.
- 【文献出处】 林产化学与工业 ,CHEMISTRY AND INDUSTRY OF FOREST PRODUCTS , 编辑部邮箱 ,1994年S1期
- 【分类号】O623.738
- 【被引频次】11
- 【下载频次】162