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流动条件下斜长石与NaCl热液相互作用的实验研究

INTERACTION BETWEEN PLAGIOCLASE AND NaCl HYDROTHERMAL SOLUTIONS─AN EXPERIMENTAL STUDY

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【作者】 曾贻善艾瑞英艾永富

【Author】 Zeng Yishan; Ai Ruiying; Ai Yongfu(Department of Geology. Beijing University. Beijing, 100871)

【机构】 北京大学地质系!北京100871

【摘要】 利用金袋热液设备,于300℃、50MPa和流动条件下(流速:7ml/h和1ml/h研究了斜长石与1mol/kgNaCl溶液的相互作用,还在同一温度压力下进行了静态实验。着重考察反应后溶液化学和长石表面化学成分的变化,以探讨钠交代作用的机理。结果表明,反应后溶液的pH值升高,Na含量降低;Si、Ca、K和Al转入溶液的特征与反应状态以及溶液流速有关;斜长石的钠交代作用涉及钙长石组分溶解和纳长石组分结晶两个过程。

【Abstract】 By using a gold-cell hydrothermal device the interaction between plagioclase and 1 mol / kgNaCl solution was studied at 300℃ and 50 MPa under flow conditions (the flow rate of solutions: 7 mL / h and 1 mL / h),and a static run was also performed at the same temperature andpressure. In order to reveal the mechanism of Nametasomatism, changes in the solution chemistryand the composition of plagioclase surface after reaction were investigated in more detail.Experimental results indicated that pH values increased and the Nacontent decreaead in the solutions after reaction,that the transformation of Si,Ca,K and Al into the solutions depends on the reactionstate and flow rate of the solutions,and that the Na-metasomatism of plagioclase involved twoprocesses:the disolution of anorthite component and the crystallization of albite component.

【基金】 国家自然科学基金;北京中关村地区联合分析测试基金
  • 【文献出处】 矿物学报 ,Acta Mineralogica Sinica , 编辑部邮箱 ,1994年01期
  • 【分类号】P611
  • 【下载频次】53
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