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金属在真空中的挥发性

Evaporation of Metals in Vacuum

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【作者】 戴永年夏丹葵陈燕蔡晓兰杨斌李金华邓智明魏宗平

【Author】 Dai Yongnian; Xia Dankui; Chen Yan Cai Xiaolan ; Yang Bin Li Jinhua; Deng Zhiming; Wei Zongping(Research Institute of Vaxuum Metallurgy and material,Metallurgy Department,Kunming Institute of Technology, Kunming 650093)

【机构】 昆明工学院冶金系真空冶金及材料研究所

【摘要】 Zn,Cd,Pb,Sb等金属的挥发速率与温度和压力的关系作了研究,结合国外的数据,归纳提出典型曲线和表达式,曲线以临界压Pcrit为界分两部分,高于Pcrit,残余气体起主要作用,金属挥发速率ω,随压力增大而减小,有logω=a一bp残;小于Pcrit时,金属的蒸气压起决定作用,ω在一定温度时为定值,此规律对实践有重要意义,如确定作业的真空度,温度,加大设备生产率,不污染环境,在真空中不氧化金属,不使金属溶解气体,还可以脱除金属中的气体等。

【Abstract】 The relationships of evaporation rate(ω)of Zn,Cd,Pb,Sb with temperature and pressure werestudied.Referins to a great deal of foreign data,typical curve and equations arc suggested.Thc curve is divided into two parts by critical pressure Pcrit.When the pressure of chamber P is larger than Pcrit residualgas plays an important role,logω=a bPresidure. And when P < Pcrit, vapor pressure of metals makes decisiverole and ω,is a constant at certain temperaturc.The results of the study are of practical usc for determining vacuum degree and temperature of a process,increasins the productivity of the equipment.dgasingthe metals with no pollution to enviroment,no oxidization to metal.and no gas solution in metal.

【基金】 云南省应用基础研究基金支持项目
  • 【分类号】TG113.22
  • 【被引频次】53
  • 【下载频次】652
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