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单向碳纤维/热解碳复合材料的高温蠕变行为
CREEP BEHAVIOUR OF AN UNIDIRECTIONAL C_F/C_P COMPOSITE AT HIGH TEMPERATURES
【摘要】 用化学气相沉积热解碳制备了一种单向T300(PAN)碳纤维增强复合材料,在1900-2350℃范围内测定材料的蠕变性能。用红外测温仪测量温度,温度波动控制在上±2℃内。经计算激活能为84.8kJ/mol,蠕变激活体积为0.754nm~3。在1900,2050,2200和2350℃的蠕变摩擦应力分别为127,115,95.6和90.3MPa。外推得知,蠕变摩擦应力为零时的温度为3375℃,约与碳的升华温度相当。
【Abstract】 Creep behaviour of the composite made of an unidirectional T300(PAN) carbon fibre reinforced CVD pyrolytic carbon was examined in range of 1990 to 2350℃. The temperature was monitored by infrared spectrometer within ±2℃. Calculational results indicate that the activation energy is 84.8 kJ / mol and activation volume is 0.754 nm3. The creep friction stresses are 127, 115, 95.6 and 90.3 MPa at 1900, 2050, 2200 and 2350℃ respectively. By extrapolation of the temperature dependence upon zero creep friction stress, the temperature seems to be about 3375℃ just to approach the sublimation one of carbon )
【Key words】 unidirectional carbon/carbon composite; high temperature creep; creep friction stress; creep activation energy; creep activation volume;
- 【文献出处】 金属学报 ,ACTA METALLRUGICA SINICA , 编辑部邮箱 ,1994年23期
- 【分类号】TG332
- 【被引频次】5
- 【下载频次】203