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Electronic Processes in Phthalocyanine Solids

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【作者】 汪茫陈红征沈菊李杨士林

【Author】 WANG Mang CHEN Hong-ZhengSHEN Ju-Li and YANG Shi-Lin(Institute of Polymer Science and Materials, Zhejiang University, Hangzhou 310027, PRC)

【机构】 Institute of Polymer Science and MaterialsZhejiang UniversityHangzhou 310027PRCPRC

【摘要】 <正> The positive or negative photoconductivity effects are found between the component of phthalocyanine dimixing composites and the photoconductivity by dimixing method. The relations between the crystalline forms and electronic structure of the composites and the photoconductivity are further studied through X-ray and XPS. The results indicate that the composites may be a kind of new uniform eutectic composites, which can enhance or reduce the partial charge transfer processes from phthalocyanine rings to metals, and the processes are exactly correspondent with the positive or negative photoconductivity effects. A model of gradually transferred charge in the phthalocyanine solids is put forward, which can better explain the electronic processes in the phthalocyanine solids.

【Abstract】 The positive or negative photoconductivity effects are found between the component of phthalocyanine dimixing composites and the photoconductivity by dimixing method. The relations between the crystalline forms and electronic structure of the composites and the photoconductivity are further studied through X-ray and XPS. The results indicate that the composites may be a kind of new uniform eutectic composites, which can enhance or reduce the partial charge transfer processes from phthalocyanine rings to metals, and the processes are exactly correspondent with the positive or negative photoconductivity effects. A model of gradually transferred charge in the phthalocyanine solids is put forward, which can better explain the electronic processes in the phthalocyanine solids.

【基金】 Project supported by the National Natural Science Foundation of China;by the Science Foundation of Zhejiang University
  • 【文献出处】 Science in China,Ser.A ,中国科学A辑(英文版) , 编辑部邮箱 ,1994年04期
  • 【分类号】O482
  • 【被引频次】3
  • 【下载频次】26
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