节点文献
RE(NO3)3·(GLy)3·nH2O配合物的合成和表征
SYNTHESESX AND CHARACTERIZATION OFRE(NO3)3 . (Gly)3 . nH2O
【摘要】 本文在水溶液中合成了镧、镨、钐和钆四种稀土硝酸盐与甘氨酸的固态配合物。化学分析表明,它们的化学组成分别是La(NO_3)_3·(GLy)_3·H_2O、Pr(NO_3)_3·(GLy)_3·H_2O、Sm(NO_3)_3·(CLy)_3·3H_2O和Gd(NO_3)·(GLy)_3·3H_2O。用红外光谱法和X射线衍射法测定了配合物的结构特征,表明它们是一类完全不同于稀土硝酸盐和甘氨酸的新化合物。同时,考察了配合物在几种常见溶剂中的溶解性。
【Abstract】 In this papor , the complexes of rare earth (La.Pr .Sm. Gd)Nitrate with giycine were prepored.The elecentary anaiysis showed that the compounds composition agree with La(NO3)3 . (Gly)3 .H2O. Pr(NO3)3 . (Gly)30 .H2O.Sm (NO3)3 . (Gly)3 . 3H2O and Gd (NO3)3 . (Gly)3 . 3H2O.All complexes were characterized by X-ray diffraction and infrared spotra, the data showed thatthe complex was a new compound, rather than a mixture. The sotubility of the complexes in gener.al solvents were studied consequently.
- 【文献出处】 化学研究与应用 ,CHEMICAL RESEARCH AND APPLICATION , 编辑部邮箱 ,1994年03期
- 【分类号】O641.4
- 【下载频次】44