节点文献
芘与1,4-二氰基苯形成的三分子激基复合物
Study of Triple Exciplex in the System of Pyrene and 1,4-Dicyanobenzene
【摘要】 本文用稳态和瞬态荧光光谱技术研究了花与1,4-二氰基苯体系形成三分子激基复合物的条件.规定了该体系中激基缔合物、激基复合物、三分子发基复合物的稳态荧光光谱及荧光强度随时间变化的行为和特性.测定了芘在苯溶液中的荧光衰减寿命.讨论了三分子激基复合物形成的光物理机理.
【Abstract】 Abstract In this paper, the photchemica and photophysical behaviors of a triple exciplex have been studied in the system of pyrene and 1,4-dicyanobenzene with steadystate and time-resolved fluorescence spectroscopic techniques. The fluorescence spectra, the dependence of fluorescence intensity on various times, the lifetime of pyrene were measured. A mechanism for the triple exciplex formation is tentatively proposed.
【基金】 国家自然科学基金,光化学开放实验室资助
- 【文献出处】 化学物理学报 ,CHINESE JOURNAL OF CHEMICAL PHYSICS , 编辑部邮箱 ,1994年02期
- 【分类号】O631.25
- 【被引频次】1
- 【下载频次】109