【摘要】 在ＤＢＵ的化学环境中，加热回流邻二氰基苯（以Ｐｈｎ表示，下同）和无水氯化钴的正戊醇溶液，合成了酞菁钴。考察了ＤＢＵ与Ｐｈｎ的摩尔比，回流反应时间以及搅拌等因素对酞菁钴产率及晶型的影响。酞菁钴合成的适宜条件为：以正成醇为溶剂，在ＤＢＵ：Ｐｈｎ＝２：１（摩尔比）时，回流６小时，其产率为７０．８％，Ｘ－射线粉末衍射表明为π－、ε－和β－型混晶，同时考察了上述混晶在用芳香溶剂处理时晶型的转变，结果表明，它们均向稳定的β－型晶体转变。更多还原

【Abstract】 In the chemical environment of 1.8-diazabicyclo [5, 4, 0] undec- 7-ene (DBU), cobalt phthalocyanine (CoPc) was syntesized by heating and refluxing phthalonitrile (Phn) with anhydrous cobaltous chloride in n-pentanol. Effects of DBU:Phn molar ratio. refluxing time and stirring on yield and crystalline modification of CoPc were studied. The suitable condition for CoPc synthesis was found to be: DBU: Phn (molar ratio)=2:1, n-pentanol as the solvent, refluxing 6 hrs. This condition yielded 70.8%.X-ray power diffraction proved to be π-. ε- and β-mixed crystal forms. At the same time, changes of above-mentioned mixed crystal forms were inspected with aromatic solvent handling products. The results stated clearly that they equally changed into a stable β-form.更多还原