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手性热变色液晶的合成及配方Ⅰ.光活性对烷基和对烷氧基苯甲酸的烷基酚酯类
Syntheses and Formulations of Thermotropic Color Liquid CrystalsⅠ.Optically Active p-Alkyl and ρ-Alkoxy Benzoic Phenol Esters
【摘要】 以新的路线合成了两类文题化合物共七个液晶单体,合成了催化剂(1,3-双-(二苯基膦基)丙烷-二氯化镍)和光活性中间体(S)-2-甲基丁基苯酚,获得了较高的产率及纯度。经元素分析、质谱和红外光谱分析确证了化合物的分子结构,测定了其液晶相态。进行了配方尝试,得到了对温度变化敏锐的热变色液晶材料,具有较好的应用前景。
【Abstract】 Seven chiral theamotropic liquid crystals were synthesized with a series of new methods.Ni(dppp)Cl2,an important catalyst in Grignard Reaction,a11d p-(S)-2-methyl-butyl phenyl,an important inteamediate,were synthesized with a higher yield and purity. Their structures were determined with 1R,MS and element analysis.By using these compounds,a series of theamotropic color liquid crystal materials were obtained.
【关键词】 液晶;
热色液晶;
有机合成;
【Key words】 liquid crystal; thermotropic color liquid crystal; organic synthesis;
【Key words】 liquid crystal; thermotropic color liquid crystal; organic synthesis;
【基金】 国家自然科学基金
- 【文献出处】 华东理工大学学报 ,JOURNAL OF EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY , 编辑部邮箱 ,1994年01期
- 【分类号】O753.2
- 【被引频次】9
- 【下载频次】170