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氟硼酸废水的常压加热处理及机理初探

THE STUDY ON Fe (Ⅲ) PROCESS IN THE TREATMENT OF WASTEWATER CONTAINING FLUOROBORIC ACID

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【作者】 黄昕赵一先郑剑李定邦潘金芳黄雪娟张大年

【Author】 Huang Xin Zhao Yixian Zheng Jian Li Dingbang Pan Jaifang Huang Xuejuan Zhang Dantan(Research Institute of Environmental Engineering. East China University of Science and Technology, Shanghai. 200237)

【机构】 华东理工大学环境工程研究所!上海200237华东理工大学环境工程研究所!

【摘要】 本文研究了高浓度氟硼酸废水在常压加热下的铁盐法处理工艺.对添加铁盐的作用机理作了初步的探讨,认为Fe(Ⅲ)的投加催化了BF4- 的酸性水解,并与F形成了稳定的氟-铁络合物,从而有效地促进了BF4-的水解.

【Abstract】 The methods with addition of Fe (Ⅲ) under normal pressure and middle temperature in the treatment of waste water containing fluoroboric acid of high concentration were discussed. It was considered that the mechanism of the Fe (Ⅲ) process mainly includes two aspects; acid catalysis and the formation of stable iron-fluro complex.fluoroboric acid, wastewater, mechanism, Fe (Ⅲ).

【关键词】 氟硼酸废水机理Fe(Ⅲ)
  • 【文献出处】 环境化学 ,Environmental Chemistry , 编辑部邮箱 ,1994年04期
  • 【分类号】X781
  • 【被引频次】2
  • 【下载频次】121
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