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聚合氯化铝对水中微量铬(Ⅳ)的富集

CONCENTRATION OF MICRO AMOUNTS OF CHROME(Ⅵ) IN WATER WITH POLY-ALUMINIUM CHLORIDE

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【作者】 罗玉忠; 于晓梅;

【Author】 Luo Yuzhong Yu Xiaomei(Istitute of Evironmental Chemistry, Southwest China Normal University, Chongqing, 630715)

【机构】 西南师范大学环境化学研究所!重庆; 630715;

【摘要】 本文研究了聚合氯化铝作为一种新的无机吸附共沉淀剂对水中微量铬(Ⅵ)的富集和测定,实验表明,它能有效地富集水中做量铬(Ⅵ),1.5g聚合氯化铝在1000ml溶液中(pH7—8,铬(Ⅵ)浓度0—500μg/1),搅拌速度在300r/min左右,搅拌间10min时,铬(Ⅵ)的吸附率在95%以上,用分光光度法满意地实现了对河水中微量铬(Ⅵ)的测定.结果表明:铬(Ⅵ)的加入回收率≥94%,测定的相对标准偏差≤3%.

【Abstract】 As a new inorganic coprecipitator poly aluminium chloride (PAC) can be used to concentrate chrome(Ⅵ) in water. It was found out that PAC. Micro amounts of chrome (Ⅵ) in water can be efficiently concentrated using 1.5g PAC in 1000ml solution (pH7-8, 0-500ug/l). When stirring speed is 300r/min and stirring time is l0min, the adsorption rate is greater than 95%, The good results of determination for micro amounts of Cr(Ⅵ) in river has been achieved by using spectrophotometry. Recovery of Cr(Ⅵ) is greater than 94% and relative standard deⅥation is equal or less than 3%.

【关键词】 铬; 絮凝剂; 预富集;
【Key words】 chrome; coagulant; preconcentration.;
  • 【文献出处】 环境化学 ,Environmental Chemistry , 编辑部邮箱 ,1994年01期
  • 【分类号】X703
  • 【被引频次】3
  • 【下载频次】82
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