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含磷共聚酯的合成及性能研究
INVESTIGATION ON THE SYNTHESIS AND PROPERTIES OF COPOLYESTRS CONTAINING PHOSPHORUS
【摘要】 用添加含磷共聚单体法合成了三种新四的含磷共聚酯。对萃洗后的反应产物进行了红外测试,对合成的反应条件进行了初步研究,并对所得产物的性能进行了对比。结果表明,含磷共聚单体的引入使共聚酯的玻璃化转变温度和熔点较聚酯降低,而冷结晶温度和结晶速度的变化则随引入的改性组分的不同而异。共聚酯的阻燃性、抗静电性均得到改善,染色性能也有所改善,表明该类共聚酯有可能用于制备多功能涤纶。
【Abstract】 n this paper,three kinds of copolyesters containing phosphorus have been synthesized and identified with IR.Their properties have also been investigated.The results showed that with the increase of the third compo-nent,the T_g and T_m of the polymer decreased,the T_c and crystallization rate changes mainly depand on thestructure of the third component.The properties of antistatic,flame resistance,dyeability of the copolyesterswere obviously improved.
- 【文献出处】 合成纤维工业 ,CHINA SYNTHETIC FIBER INDUSTRY , 编辑部邮箱 ,1994年04期
- 【分类号】O633.14
- 【被引频次】8
- 【下载频次】108