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烯丙基环戊二烯的制备和结构表征
PREPARATION AND STRUCTURE CHARACTERIZATION OF ALLYL-CYCLOPENTADIENE
【摘要】 用环戊二烯基钠与烯丙基溴反应制取烯丙基环戊二烯(A-CPD),研究了反应条件和贮存时间对A-CPD收率的影响,测定了A-CPD的结构和稳定性。结果表明,A-CPD存在两种异构体,在室温下极易发生Diels-Alder反应。
【Abstract】 The effect of reaction conditions on the yield of allyl-cyclopentadiene(A-CPD)was studied in the preparation of A-CPD by the syntheitc reaction between the cyclopentadienyl sodium and the allyl bromide.The structure and the stability of the A-CPD was determined.The result showed that A- CPD had two isomers,and could easily occur the Diels-Alder reaction in the room temperature.
【关键词】 环戊二烯基钠;
烯丙基环戊二烯;
Diels-Alder反应;
【Key words】 cyclopentadienyl-sodium; allylcyclopentadiene; Diels-Alder reaction;
【Key words】 cyclopentadienyl-sodium; allylcyclopentadiene; Diels-Alder reaction;
【基金】 国家自然科学基金
- 【文献出处】 合成橡胶工业 ,CHINA SYNTHETIC RUBBER INDUSTRY , 编辑部邮箱 ,1994年03期
- 【分类号】O624.12
- 【被引频次】13
- 【下载频次】291