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二元溶液热力学性质的表达形式
On the Formalism of Macroscopic Laws of Thermodynamic Properties of Binary Solution
【摘要】 根据连续性原理,宏观热力学量是微观统计的结果和最小作用原理,导出关于混合自由焓△G~M 的微分方程,对于不同的本征值可解出理想溶液,正则溶液及亚规溶液等十分有意义的表达形式.
【Abstract】 According to the principle of continuity and least action,and the fact that thermo- dynamic quantites are the statistical results of microstates,a differential equation for the macroscopic laws of binary solution is deduced.For the corresponding eigen value,the meaningful formalism of idea solution,regular solution,sub-regular solution and so on are obtained.
- 【文献出处】 河北机电学院学报 , 编辑部邮箱 ,1994年04期
- 【分类号】TK122
- 【下载频次】49