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反相悬浮与非均相水解法合成阴离子聚丙烯酰胺的研究
Studies on the synthesis of APAA with ultra-high molecular weight by inverse suspension and heterogeneous hydrolysis Polymerization
【摘要】 采用反相悬浮与非均相水解相结合的方法合成了分子量大于 107 的阴离子聚丙烯酰胺(APAA)。研究了水解度(HD)与水解时间及体系 叫的关系、不同水醇比(V_水/W_醇)条件下 HD与时间的关系,HD与温 度的关系,同时研究了APAA在溶液中的粘性行为,讨论了分子量的 测定方法。
【Abstract】 A Powdery and rapidly dissolved APAA with Ultra-high mol. -wt. has been prepared by inverse suspension and heterogeneous hydrolysis polymerization. Factors influencing hydrolysis degree (HD ) of PAA,such as pH. temperature. The ratio of VH2OV-OHand nNaOH/nAM have been studied. Also the viscosity of APAA solution and the methods of ■ measurement have been discussed.
- 【文献出处】 广州化学 ,Guangzhou Chemistry , 编辑部邮箱 ,1994年01期
- 【分类号】O632
- 【被引频次】7
- 【下载频次】148