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Bi12SiO20晶体核芯的形成和消除

FORMATION AND ELIMINATION OF CORES IN Bi12SiO20 CRYSTALS

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【作者】 徐学武廖晶莹沈炳孚邵培发陈显求何崇藩

【Author】 Xu Xuewu;Liao jingying;Shen Bingfu;Shao Peifa;Chen Xianqiu;He Chongfan(Shanghai Institute of Ceramics , Chinese Academy of Sciences)

【机构】 中国科学院上海硅酸盐研究所

【摘要】 对于沿〈001〉、〈110〉、〈111〉、和〈112〉4种取向提拉法生长的直径为35mm的BSO晶体进行了剖析。用阴影法和光学显微镜观察等方法揭示了BSO晶体中深色核芯与生长取向、界面形状及小面生长之间的关系。讨论了核芯形成机制和消除方法。指出通过选择适当的转速,使晶体以平的或凹的界面生长,可消除〈001〉和〈110〉取向生长的BSO晶体中的核芯:选择〈111〉和〈112〉取向生长则能有效地避免深色小面核芯的形成。此外还讨论了生长条纹、组分过冷、应力和位错等缺陷问题。

【Abstract】 The BSO crystals,35 mm in diameter,pulled along 〈001〉,〈110〉,〈111〉and〈112〉axes were dissected.The relationships among the darkened cores in the BSO crystals,growth direction,interface shape and growth of facets were revealed by methods of shadowgraph and microscopy.The mechanism of core formation and methods of core elimination were discussed.It is shown that the cores in the BSO crystals grown along〈001〉and〈110〉axes can be eliminated by selecting a proper rotation rate which makes the interface shape flat or concave,and that the darkened facet-cores can be effectively avoided by choosing〈111〉and〈112〉 growth direetions. The defects such as growth striation constitutional supercooling,stress and dislocation are also dis-cussed in the paper.

  • 【文献出处】 硅酸盐学报 ,JOURNAL OF THE CHINESE CERAMIC SOCIETY , 编辑部邮箱 ,1994年06期
  • 【分类号】O779
  • 【被引频次】4
  • 【下载频次】75
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