【摘要】 本文研究了５，１０，１５，２０－四（对－山岗酸乙酯－ａ－氧代苯基）卟啉在气－液界面的成膜性能。在优化实验条件下制备了该化合物的多层ＬＢ膜。利用偏振ＦＴ－ＩＲ谱测定了卟琳上脂链取代基在ＬＢ膜结构中的取向。结果表明脂链轴线与载片法线间夹角为２７°。更多还原

【Abstract】 foe orientation of the aliphatlc chain components of tetra-4-oxy(2-ethylbehenate) phenylporphyrin in LB films has been measured by FT-IR polarized transmis-sion spectroscopy at different incidence angle,The following conclusions can be obtained:(1)the hydrocarbon chains take an uniaxial orientation with respect to the substrate normal;(2) the axis of the aliphatic chains makes an angle of 27° with the normal to the substrate.更多还原