【摘要】 本文采用热分析法分别测定出４０～５０℃生长的ＴＡＰ晶体（Ｉ）和５０～７０℃生长的ＴＡＰ晶体（Ⅱ）两样品于３５～１４０℃温区内均没有任何脱水及相变峰。同时分别对ＴＡＰ晶体（Ｉ）和（Ⅱ）进行Ｘ射线粉末衍射物相分析和ｘ射线双晶衍射实验，结果发现两种样品的衍射数据及衍射参数吻合较好。实验结果进一步证实，４０～５０℃下生长的ＴＡＰ晶体没有出现水合物，而且和５０℃以上生长的ＴＡＰ晶体具有相同的晶体结构。因此认为ＴＡＰ晶体生长的温度区间可以扩展为４０～７０℃下进行。更多还原

【Abstract】 This article has found that there are no hydroextra and phase change peak in TAP(I)and TAP(Ⅱ)crystal under 35～100℃temperaturerange by means of thermal analysis. Through X-raydiffraction experiments on TAP crystal developedunder 40～50℃ and 50～70℃ temperature rangesrespectively,we discoverd that the diffrected dataand diffrected parameter of the above two specimenshave a rather good coincidence. Therefore,wedraw the conclusion that there exists no hydrate inTAP crystal developed under 40～50℃ temperaturerange.更多还原