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NH4+对ZrO2超细粉性能的影响

Influence of NH4+ Ion on Charactor of ZrO2 Ultra-Powder

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【作者】 卢德新李佐宜

【Author】 Lu Dexing, Li Zuoyi (Department of Solid State Electronics, Huazhong University of Science and Technology, Wuhan, 430074, China)

【机构】 华中理工大学固体电子学系!武汉430074

【摘要】 本文介绍了ZrO2超细粉的制备工艺。在制备ZrO2超细粉时采用铵盐[(NH4)2SO4]作为添加剂,可以起到缓冲剂及络合剂的作用,改变了沉淀的表面电化学性质,并控制了沉淀终了时的pH值,认为如下结构胶团{[Zr(OH)4]mn(OH-),(n—x)NH4+}x-x·NH4+的生成是使ZrO2超细粉粒度变小的根本原因。

【Abstract】 The making technology of ZrO2 ultra- powder introduced, NH4+ salt was used for additives when making ZrO2 ultra-powder and which can be substitute for buffer and complex agents, thus it changed the superficial electrochemistry charactor of the sedimentation also it controled the value of pH at the end of sedimentation. The following structure of colloidal particles production was recognized as the radical cause of making the size of ZrO2 ultra- powder become small, ([Zr (OH)4]mn (OH-), (n- x)NH4+}x-x·NH4+.

【关键词】 ZrO2超细粉添加剂胶团
【Key words】 ZrO2 ultra-powderadditivescolloidal particles
  • 【文献出处】 功能材料 ,Journal of Functional Materials , 编辑部邮箱 ,1994年04期
  • 【分类号】TB383
  • 【被引频次】8
  • 【下载频次】56
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