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磺化酞菁镓的二聚现象研究
STUDY ON THE AGGREATION OF GA-SULFO PHTHALOCYANINE
【摘要】 采用分光光度法研究了磺化酞菁镓的二聚现象;测定了二聚常数k_d,讨论了PH值、离子强度、水、温度等因素对k_d的影响,研究结果表明:磺化酞菁镓的二聚反应可表示成:且磺化酞菁镓的二聚常数随着离子强度、磺酸基数目、水的浓度的增加而增加。
【Abstract】 The aggregation of Ga-sulfopthlocyanine+ has been studied.Dimerization constantsare reported.The effects of pH, ionic strength,water,temperature, and sulfonation numberon the aggregation are also discussed.The experimental results show that Ga-sulfophth-alocyanine aggregative reaction can be expressed as follows:It also shows that the greater the ionic strength,the sulfonation number,and the concentration of water the greater the dimerization constants of Ga-sulfophthalocyanine willbe.
【关键词】 锭;
酞菁;
聚合;
分光光度测定;
【Key words】 gallium; phthalocyanine; aggregation; spectrophotometry To whom correspondence should be addressed.;
【Key words】 gallium; phthalocyanine; aggregation; spectrophotometry To whom correspondence should be addressed.;
- 【文献出处】 感光科学与光化学 ,PHOTOGRAPHTC SCIENCE AND PHOTOCHEMISTRY , 编辑部邮箱 ,1994年01期
- 【分类号】O656.9
- 【被引频次】17
- 【下载频次】79