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固相接枝聚丙烯的晶态结构和热行为
EFFECT OF SOLID PHASE GRAFT POLYMERIZATION ON CRYSTAL STRUCTURE AND THERMAL BEHAVIOUR OF POLYPROPYLENE
【摘要】 采用广角X射线衍射(WAXD)和差示扫描量热法(DSC),研究了固相接枝反应对聚丙烯晶态结构和热行为的影响。结果表明,聚丙烯用马来酸酐固相接枝后,晶面间距基本不变,微晶尺寸增大,熔点降低,结晶度略有提高。
【Abstract】 The effect of solid phase graft copolymerization on crystal structure and thermal behaviour of polypropylene was studied by WAXD and DSC method. The results show that the crystallite sizes of polypropylene increase due to the solid phase graft copolymerization of maleic anhydride,but the crystallographic interplanar spacing invaries,moreover,the melting point of modified polypropylene depresses,and its crystallity slightly increases.
【关键词】 聚丙烯;
马来酸酐;
固相接枝反应;
晶态结构;
热行为。;
【Key words】 s:polypropylene; maleic anhydride; solid phase graft copolymerization; crystal structure.thermal behaviour.;
【Key words】 s:polypropylene; maleic anhydride; solid phase graft copolymerization; crystal structure.thermal behaviour.;
- 【文献出处】 高分子材料科学与工程 ,POLYMERIC MATERIALS SCIENCE & CNGINEERING , 编辑部邮箱 ,1994年06期
- 【分类号】O632.12
- 【被引频次】53
- 【下载频次】184