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相转移催化苯乙酸新合成方法的研究
Study about the New Synthetic Method of Phenylacetic Acid with Phase Transfer Catalyst
【摘要】 在相转移催化条件下氯千的羰基化反应,产物苯乙酸的产率是60%;羰基化试剂Co(co)4是在常温,常压下由Co(NO3)2制得,不须分离钝化,直接使用,是一种合成苯乙酸的新方法。本文对影响反应的因素进行了探索。
【Abstract】 This paper was about the carbonylation reaction of benzyl chloride with phase transfercatalyst.The yield of phenylacetic acid was 60%。Carbonylation regent was prpared under ordinarytemparature and presure,which was directiy utilized without separating and purifying. It was the newmethOd of Synthesizing of phenylacetic acid。 The factors of influence on the reaction were also dis。cussed
【关键词】 羰基钴离子;
硝酸钴;
羰基化;
相转移催化。;
【Key words】 cobaIt carbonyl anion; cobaIt nitrade; carbonylation; phase transfer catalyst;
【Key words】 cobaIt carbonyl anion; cobaIt nitrade; carbonylation; phase transfer catalyst;
- 【文献出处】 广东医药学院学报 , 编辑部邮箱 ,1994年01期
- 【分类号】R914
- 【下载频次】65