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GDX树脂和二氧六环的理化性质对水中酚类污染物富集洗脱性能的影响

The Effect of the Physicochemical Properties of GDX Resin and Dioxane on the Performance of Adsorption and Elution for Trace Phenols from Water

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【作者】 包南高连存王吉顺王淑仁

【Author】 BAO Nan; GAO Lian-Cun; WANG Ji-Shun; WANG Shu-Ren(Center of Environmental Science, Shandong University, Jinan, 250100)

【机构】 山东大学环境科学中心

【摘要】 以9种一元酚为吸附质,系统讨论了GDX-502和二氧六环的理化性质对酚类富集及洗脱性能的影响.结果表明,GDX-502使用前的溶剂预处理具有净化树脂和改变树脂的孔结构的双重功能,用本文方法对GDX-502进行溶剂预处理,可使树脂获得有利于酚类富集与洗脱的孔结构,该树脂对水中酚类的富集作用是以VanderWaals力和较氢键弱的π-键合作用力为基础的物理吸附,而二氧六环洗脱酚类的实质是氢键作用.

【Abstract】 GDX-502 resin, commercially availabe in China, was an excellent adsorbent and dioxane was an excellent eluant for trace phenols in water. In this paper, the relationship between the physicochemical properties of GDX resins and the adsorption characteristics, the physicochemical properties of dioxane and the elution characteristics were investigated. Adsorption-desorption mechanism was discussed briefly by means of IR, Raman and 1H NMR spectra. The pore parameters of GDX resins were determined by mercury porosimeter.It would be raised for concentration efficiency when the dry resins were treated by a series of solvents under the experiment conditions.

【关键词】 GDX树脂吸附性能
【Key words】 PhenolsGDX resinAdsorption characteristic
【基金】 国家环保局科技三项费用资助
  • 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,1994年12期
  • 【分类号】X132
  • 【被引频次】6
  • 【下载频次】85
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