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聚醚醚酮/聚醚砜嵌段共聚物的动态力学行为
Dynamic Mechanical Behavical Behaviour of Polyethereetherketone/Polyethersulfone Block Copolymers
【摘要】 本文以聚醚醚酮和聚醚砜两种齐聚物为原料合成了聚醚醚酮/聚醚砜嵌段共聚物,用动态力学谱仪对其进行了动态力学性能研究。从无定形共聚物样品对数减量-温度谱图中观察到清晰而完全分离的玻璃化转变内耗峰和非晶态向结晶态转变(α'转变)内耗峰,确认α'转变发生在冷结晶初期而后很快减弱。
【Abstract】 Polvetheretherketone/polyethersulfone block copolymers were prepared by condensation of two oligomers and their dynamic mechanical behaviour were investigated.Two ditstinct relaxation peaks i.e.βand α’,were observed in amorphous copolymer samples and it was found that the α’ relaxation can be attributed to low temperature crystallization of PEEK.
【关键词】 PEEK/PES嵌段共聚物;
动态力学行为;
转变行为;
【Key words】 PEEK/PES block copolymer; Dynamic mechanical behaviour; Transition behaviour;
【Key words】 PEEK/PES block copolymer; Dynamic mechanical behaviour; Transition behaviour;
【基金】 国家自然科学基金
- 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,1994年05期
- 【分类号】O632.32
- 【被引频次】24
- 【下载频次】157