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接触角法研究氨丙基硅烷化石英表面

Studies on the Surface Aminopropylsilanized Quartz by Contact Angle Method

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【作者】 孔祥兴张希高芒来沈家骢

【Author】 KONG Xiang-Xing; ZHANG Xi;GAO Mang-Lai; SHEN Jia-Cong(Department of Chemistry, Jilin University, Changchun,130023)

【机构】 吉林大学化学系

【摘要】 利用接触角法研究了氨丙基硅烷化石英表面的基因浓度及单分子层中单个分子的截面积。提出了氨丙基硅烷化的模型。

【Abstract】 In this paper,the concentration of amino group onto aminopropylsilanized(APS)quartz was measured by using contact angle method. Using phenol as a probe, the weak acid (phenol in CH2I2 solution)/the base(APS quartz) adsorption was studied in detail, and the surface concentration of amino group on APS surface was calculaled as 1.14 nm2/mole when the Langmuir isotherm was used. And further ,SAzoNC6OH acted as a probe, the surface adsorption concentration and molecular section area was indetified by using UV-visible absorption spectra. Comparing the area of per amino group of 0.41 nm2 from adsorption spectra measurement, a densed packing model, with hydrogen bonding existing between amino groups, was proposed.

【基金】 吉林大学分子光谱与分子结构开放实验室资助,国家教育委员会回国人员基金,吉林省科委青年基金
  • 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,1994年03期
  • 【分类号】O613.72
  • 【被引频次】9
  • 【下载频次】175
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