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二元乙丙共聚物的强化辐射交联

THE ENHANCED RADIATION CROSSLINKING OF ETHYLENE-PROPYLENE COPOLYMER

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【作者】 许云书毛欣根郭高品付依备

【Author】 Xu Yunshu;Mao Xingen; Guo Gaopin; Fu Yilei (Southwest Institute of Nuclear Physics and Chemistry. Chengdu 610003)

【机构】 西南核物理与化学研究所

【摘要】 研究了添加少量三甲基丙烯酸三羟甲基丙烷酯条件下二元乙丙共聚物的辐射交联。结果表明,交联密度正比于剂量和单体含量,而溶胶分数与剂量间的关系偏离Charlesby-Pinner关系式。通过引进假设,基于统计理论结果提出了一个半经验式。用该式能较好地解释实验结果,并能与文献数据相符。

【Abstract】 The radiation crosslinking of ethylene-propylene copolymer containing trimethylolpropane trimethacrylate was investigated.Results showed that crosslinking density varied proportionally with dose and monomer contents, and the relationship between sol fraction and dose deviated from Charlesby-Pinner Equation. Based on statistical theory results, an assumption was suggested in and a semi-experimental formula was obtained which agreed well with experiments.

  • 【文献出处】 辐射研究与辐射工艺学报 ,JOURNAL OF RADIATION RESEARCH AND RADIATION PROCESSING , 编辑部邮箱 ,1994年03期
  • 【分类号】O631.34
  • 【被引频次】12
  • 【下载频次】73
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