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秩消因子分析-荧光激发发射光谱法测定稀土混合物中的铈
Determination of Cerium in Rare Earth Mixtureby Using Rank Annihilation Factor Analysis-Fluorophotometry
【摘要】 本文用秩消因子分析法(RAFA)对稀土铈、试混合体系的荧光激发发射光谱矩阵(EEM)进行分析,利用稀土元素的荧光光谱特性,在不考虑其它共存元素的情况下,对已知存在的组分铈(含量为0.112~0.559μg/mL)进行测定,其回收率为93.3%~102%
【Abstract】 An application of rank annihilation factor analysis(RAFA)for the quantitative analysis of Ce in somerare earth mixtures containing cerium and terbiumusing the excitation-emission matrix(EEM)acquiredby a fluorophotometer is described.The content ofcerium in several mixtures was determined successfullywithout regard for the existence of terbium.A good recovery(99.3%~100.2%)is obtained when theconcentration range of cerium in the mixture is from0.112 to 0.559/mL.
【关键词】 秩消因子分析;
荧光光谱;
铈测定;
铽;
【Key words】 Rank annihilation factor analysis; fluorophotometry; cerium determination;
【Key words】 Rank annihilation factor analysis; fluorophotometry; cerium determination;
【基金】 国家自然科学基金
- 【文献出处】 分析试验室 ,ANALYTICAL LABORATORY , 编辑部邮箱 ,1994年06期
- 【分类号】O614.332
- 【被引频次】5
- 【下载频次】117