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用2-(2′-咪唑偶氮)苯酚-4-磺酸作显色剂测定铁

Spectrophotometric determination of Fe(Ⅱ)with2-(2’-imidazolylazo)phenol-4-sulfonic Acid(IAP-4S)

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【作者】 冯建章史金梅童沈阳

【Author】 Feng Jianzhang,Shi Jinmei and Tong Shenyang(De-partment of Chemistry,Peking University,Beijing100871)

【机构】 北京大学化学系

【摘要】 本文研究了咪唑偶氮苯酚-4-磺醚与Fe(Ⅱ)的显色反应条件,应用拟定的方法测定了菠菜、芹菜、人发、天然水中微量铁的含量,回收率在95%以上,结果令人满意。

【Abstract】 The reaction of IAP-4S with Fe(Ⅱ)has beenstudied for the determination of iron in the biologicaland environmental samples.Beer’s law was obeyed foriron in the range of 0~50 μg/25mL. The apparentmolar absorptivity of the complex at 692nm was 1.18×10 ̄4L; mol ̄(-1).cm ̄(-1).The relative standard deviationfor nine determinations was 1%for 10 μg/25mL ofiron,The method has been applied to the determina-tion of iron in spinach,celery,human hair,naturaland well waters,and excellent results were obtained

  • 【文献出处】 分析试验室 ,ANALYTICAL LABORATORY , 编辑部邮箱 ,1994年03期
  • 【分类号】O614.811
  • 【被引频次】6
  • 【下载频次】33
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