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阴离子交换纤维素分离富集石墨炉原子吸收法测定地质样品中微量铂和铑
Determination of Trace Platinum and Rhodium in Geological Samples by Graphite Furnace Atomic Absorption Spectrometry After Their Separation and Enrichment With VS- Ⅱ Type Anion Exchange Fibrin
【摘要】 本文研究了VS-Ⅱ型强碱性阴离子交换纤维素的吸附性能,发现铂和铑在盐酸介质中易形成稳定的氯络阴离子,吸附于阴离子纤维素进行苗集,并与大部分贱金属元素分离。采用酸性硫脲作为淋洗剂,可以定量地洗脱纤维素上的铂和铑,而纤维素不被破坏,重新处理使用。本法对铂和铑的回收率分别为:95%~103%;92%~98%,线性范围0~100ng/ml。
【Abstract】 The adsorbent performance of VS- Ⅱ type anion exchange fibrin has been studied. The stable chlorocomplex anion of Pt and Rh can form easily in HCl medium, and be adsorbed on the fibrin to enrich, and be separated from many other base metals. When acidic thiourea is used as eluting agent, Pt and Rh can be recovered quantitatively. The fibrin can be retreated and reused easily. The recovery of Pt and Rh is 95%-103% and 92%-98%. respectively. The linear range is 0-100 ng/ml.
【关键词】 石墨炉原子吸收;
阴离子交换纤维素;
铂;
铑;
【Key words】 Graphite furnace atomic absorption spectrometry; Anion exchange fibrin; Platinum; Rhodium;
【Key words】 Graphite furnace atomic absorption spectrometry; Anion exchange fibrin; Platinum; Rhodium;
【基金】 地矿部行业基金资助课题
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1994年02期
- 【分类号】O657.3
- 【被引频次】13
- 【下载频次】95