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流动注射催化光度法测定痕量铜
Flow Injection Catlytic Spectrophotmetrie Determination of Tract Coppr(Ⅰ)
【摘要】 本文基于在碱性介质中,铜(Ⅱ)对过硫酸铵氧化还原型酚酞有明显的催化作用,采用流动注射停流技术,优化了实验条件,建立了流动注射催化光度法测定痕量铜的新方法,线性范围为0~500ng·ml-1,检出限为94pg·ml-1,用于地下水及环境标准样品的分析均获得结果。
【Abstract】 A flow injection catalytic spectrophotmetric method based on the oxidzation ofreduced -phenolphthalein with ammonium persulphate by means of Cu( II ) as cala-for the determination oftrace Cu( II ) in borax solution has been developed. Theof determination is 0-500ng Cu( II ) /ml and detection limit is 0. 094ngg/The method to determine copper( II ) in surrornding spectrum and water sam-s with satisfactory results. The analytial velocity 65s/h.
【关键词】 流动注射催化光度法;
还原型酚酞;
铜(Ⅱ);
【Key words】 Flow injection catlytic spectrophotmetric method; reduced-phenolphtlmlein; copper(Ⅱ);
【Key words】 Flow injection catlytic spectrophotmetric method; reduced-phenolphtlmlein; copper(Ⅱ);
- 【文献出处】 淮北煤师院学报(自然科学版) ,Journal of Huaibei Industry Teachers College (Natural Sciences Edition) , 编辑部邮箱 ,1994年04期
- 【分类号】O657.3
- 【下载频次】25