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掺杂离子在LHPG单晶光纤中的分布
THE STUDY OF DOPANT DISTRIBUTION IN THE LHPG-GROWN SINGLE CRYSTAL FIBERS
【摘要】 用电子能量色散谱(EDS)分析了Nd(3+),Er(3+)和Cr(3+)等掺杂离子在YAG单晶光纤中的分布,实验发现:掺杂离子的分凝系数不同,其分布规律也不同.根据晶体的熔液生长理论,导出了掺杂离子分布方程,它与实验结果相符较好.
【Abstract】 Single crystal fibers (SCF) have the intrinsic attributes of both crystal and fiber. The properties of SCF, like that of bulk crystal, can be affected by the dopants distribution to a great extent. In this work the sampe of single crystal fibers, Nd3+: YAG (Ke<1), Er3+: YAG (Ke = 1) and Cr3+: YAG (Ke>1),are grown by the Laser Heated Pedestal Growth (LHPG) method. Electronic Dispersion Spectra (EDS) is used to analyse the dopants concentration. It’s found that the profiles of dopant distribution are determined by the effective distribution coefficients of the dopants.Equation describing the dopants distribution are derived from the theory of meltcrystal growth, and it may be written in the follow form:Cs(z)=C0[3β/(β+2)][1+(Ke-1)exp(-z /σ)]·[1-(1-1 /β)(2r2-r4)] it’s obvious that the dopant distribution in the LHPG-grown SCF is affected by the effective distribution coefficient of the dopant. The axial average concentration does not change after a certain length of the fiber no matter what Ke is. The radial distribution like that shown in Fig.3, when Ke>1 , the concentration in the centre is higher than that at the border; when Ke<1, the conentration in the centre is lower than that at the border; and when Ke = 1, the dopant is well distributed.
【Key words】 dopant distribution; laser heated pedestal growth (LHPG); single crystal fiber; distribution coefficient;
- 【文献出处】 材料研究学报 ,CHINESE JOURNAL OF MATERIAL RESEARCH , 编辑部邮箱 ,1994年05期
- 【分类号】TN305.3
- 【被引频次】2
- 【下载频次】50