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在极浓非水体系中ZSM-35沸石的合成及表征
SYNTHESIS OF ZSM-35 ZEOLITE IN THE EXTREMELY DENSE SYSTEM AND ITS CHARACTERIZATION
【摘要】 在极浓非水体系中ZSM-35沸石的合成及表征李建权,刘光焕,董晋湘,孙继红(太原工业大学精细化工研究所,太原030024)关键词极浓体系,非水体系,ZSM-35沸石,合成,表征水热法已广泛用于沸石合成工业过程,尤其是用有机胺作模板剂制备出性能优越的Z...
【Abstract】 SM-35 zeolite was first synthesized in the extremely dense nonaqueous system. in which the weight ratio of solid (aluminosilicate gels and NaOH ) to liquid (ethylenediamine and triethylamine ) mixture achieves 2. 9 or the SiO2/ (C2H5)3N ratio and SiO2/NH2(CH2)2NH2 ratio are 8. 7 and 3. 9 respectively. The adsorption and catalytic behaviours of ZSM-35 zeolite prepared by this method were much improved. Particularly,the separation procedure was not needed after the crystallization.At the same time, this method could decrease the consumption of organic compounds by a big margin.On the other hand, adding paucity ofwater and seeds respectively could increase the crystallization rate and decrease the nucleation time.
【Key words】 extremely dense system; nonaqueous system; ZSM-35zeolite; synthesis; characterization;
- 【文献出处】 催化学报 ,CHINESE JOURNAL OF CATAL YSIS , 编辑部邮箱 ,1994年04期
- 【分类号】O643.36
- 【被引频次】3
- 【下载频次】122