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偶氮胂Ⅲ分光光度法测定铬(Ⅲ)的研究
Study on the Spectrophotometry Arsenazo(Ⅲ) Determination of Cr(Ⅲ)
【摘要】 研究了偶氮胂与铬(Ⅲ)的显色反应,结果表明:加热煮沸5mim,配合物形成完全配合物最大吸收波长610nm,摩尔吸光系数为2.1×10 ̄4L/mol·cm,铬(Ⅲ)的测定范围在0~60μg/50mL内符合朗白-比耳定律。本法回收率95%~100%。应用于天然木和工业废水中铬(Ⅲ)的直接测定。
【Abstract】 The Chromogenic reation of Cr(Ⅲ) with arsenazo Ⅲ have been studied.The results show that complex formation reation can be complete by heating at 100℃ for 5 min. The most absorption band of the complex lies at 610 nm. The apparent molar absorptivity is 2.1× 10~4L mol. cm. Lambert-Beer law is obeyed for Cr(Ⅲ) in the concentration range 0~60 mg/50 mL. The range of the recovery is 95%~100%. The metbod has been applied to the determination of Cr(Ⅲ) in water and industriat water water.
- 【文献出处】 北京工业大学学报 ,JOURNAL OF BEIJING POLYTECHNIC UNIVERSITY , 编辑部邮箱 ,1994年02期
- 【分类号】X832
- 【被引频次】11
- 【下载频次】264