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计算极谱法同时测定镉镍的研究
Use of Kalman Filtering for the Polarographic Determination of Cd and Ni
【摘要】 采用普通极谱仪与计算机联机技术,用卡尔曼滤波处理以KSCN为支持电解质的Cd2+和Ni2+混合溶液的示波极谱重叠波。实验表明,极谱可逆波具有较好的加和性,可采用计算极谱方法对多组分(尤其是难以分开的重叠波)进行同时测定。
【Abstract】 The overlapping polarographic waves of Cd and Ni in 1.0 mol/L KSCN electrolyte can be resolved by using kalman filtering and a method for determing both elements simultaneously is developed. The method is simple and accurate. The average recoveries for Cd( Ⅱ)and Ni(Ⅱ )were 94. 50% and 99. 97% respectively.
【关键词】 镉;
镍;
计算极谱法;
卡尔曼滤波;
多组分同时测定;
【Key words】 cadmium and nickel determination; kalman filter; polarography;
【Key words】 cadmium and nickel determination; kalman filter; polarography;
- 【文献出处】 岩矿测试 ,Rock and Mineral Analysis , 编辑部邮箱 ,1993年01期
- 【被引频次】2
- 【下载频次】23