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导电聚合物单体的光电聚合
PHOTOELECTROCHEMICAL POLYMERIZATION OF CONDUCTING POLYMER MONOMERS
【摘要】 <正> 苯胺、吡咯和噻吩等是重要的导电聚合物单体.光照可促进低聚物的形成,电化学技术可方便地实现单体的电聚合.目前,有关导电聚合物单体的光电聚合的报导还很少.本文研究征水溶液中、铂金属基底上,苯胺、吡咯和噻吩等单体的光电聚合过程.
【Abstract】 The photoelectrochemical polymerization process:monomer first polymerizes intolow polymer and then the low polymer may be oxidized into polymerfilm.monomer→low polymer→polymerfilmIrradiation can accelerate the formation of low polymer.The rate of the firststep for pyrrole and thiophene is slow,and the second step for aniline is slow.When the film is formed,it can speed up the rate of film formation.
【关键词】 光电聚合;
导电聚合物;
聚苯胺;
聚吡咯;
聚噻吩;
【Key words】 Photoelectrochemical polymerization; Conducting polymer; Polyaniline; Polypurrole; Polythiophene;
【Key words】 Photoelectrochemical polymerization; Conducting polymer; Polyaniline; Polypurrole; Polythiophene;
【基金】 国家自然科学基金
- 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,1993年02期
- 【被引频次】4
- 【下载频次】121