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穿过液膜的自发电势振荡

SPONTANEOUS OSCILLATION OF ELECTRICAL POTENTIAL ACROSS LIQUID MEMBRANE

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【作者】 王寿祥邱志新陈森龚建平

【Author】 Wang Shouxiang~* Qiu Zhixing Chen Sen Gong Jianping (Department of Chemistry,Shanghai Normal University,Shanghai 200234)

【机构】 上海师范大学化学系上海师范大学化学系 上海200234上海200234上海200234

【摘要】 <正> 本文研究的体系是在一个U 形玻璃管里,底部加入苦氨酸的硝基苯溶液(油相)作为人造液膜,右边支管中加入含乙醇的十八烷基三甲基氯化铵的水溶液,左边支管中加入蔗糖水溶液(或去离子水).电势振荡振幅在20—150mV 之间.根据文献报导,表面活性剂穿过油相产生界面振荡.本实验用的十八烷基三甲基氯化铵(简称C18+Cl-)是一个阳离子型表面活性剂,与苦氨酸(简称HA)接触时显橙红色,

【Abstract】 An artificial membrane consisting of pricramic acid in nitrobenzene was used asan oil phase imposed between two aqueous phases.The right one contained trimethyl-slearylammonium chloride and aicohol;and the left contained sucrose solution(orH2O).We found that this system exhibited rhythmic oscillation of electrical potential.The amplitude of the oscillations was between 20—150mV.The oscillations were ob-served even when ethyl alcohol was absent in the aqueous of trimethylslearylammoniumChloride,and the increase in amplitude of oscillations with time was found to be lessin the presence of sucrose.Some of the expremental results have been explained.

  • 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,1993年02期
  • 【被引频次】30
  • 【下载频次】30
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