【摘要】 本文合成了铑(Ⅲ)酞菁配合物,用循环伏安法研究了该配合物在二甲基甲酰胺、吡啶和二甲亚砜等有机溶剂中的电化学,并利用薄层透光电极电解;获得了该配合物四种不同氧化态时的电子光谱,并对电极反应机理及其产物进行了讨论.更多还原

【Abstract】 Rhodium(Ⅲ) phthalocyanine was prepared. It’s electrochemistry was studied in dimethylmamide, pyridine and dimethylsulfoxide. The redox mechanisms and species on the electrode were discussed. With the use of an optically thin electrode, the electronic absorption spectra of 4 different oxidation states were also reported.更多还原