节点文献
金属卟啉作为电子光谱探针的研究(Ⅰ)——卟吩衍生物与Co(Ⅱ)离子的配位反应
STUDY ON METALLOPROPHYRIN USED AS ELECTRON SPECTRUM PROBE——COORDINATION REACTION OF PROPHYRIN WITH Co (Ⅱ) ION
【摘要】 文中对两种卟吩衍生物与Co(Ⅱ)的配位机理用电子光谱进行了研究,给出了表观反应速率常数,发现该反应分两步进行并经历一个中间过渡态。
【Abstract】 Coordination reaction mechanism of two kinds of prophyrin with Co(Ⅱ) ion has been studied by using their electron spectrums. Their apparent rate constants have been given. It is discoverd that the reaction is divided into two steps, and goes through a transition state.
【关键词】 卟啉;
电子光谱探针;
钴(Ⅱ);
配位反应机理;
【Key words】 prophyrin; electron spectron probe; Co(Ⅱ) coordination reaction mechanism;
【Key words】 prophyrin; electron spectron probe; Co(Ⅱ) coordination reaction mechanism;
【基金】 山西省自然科学基金
- 【文献出处】 山西大学学报(自然科学版) ,Journal of Shanxi University (Natural Science Edition) , 编辑部邮箱 ,1993年04期
- 【分类号】O41
- 【被引频次】1
- 【下载频次】69